Synthesis and Characterization of Al-TON Zeolite Using a Dialkylimizadolium as StructureDirecting Agent
dc.contributor.author | Pergher, Sibele Berenice Castellã | |
dc.contributor.author | Lopes, Christian Wittee | |
dc.contributor.author | Villarroel-Rocha, Jhonny | |
dc.contributor.author | Silva, Bernardo Araldi da | |
dc.contributor.author | Mignoni, Marcelo Luis | |
dc.date.accessioned | 2020-07-06T18:59:59Z | |
dc.date.available | 2020-07-06T18:59:59Z | |
dc.date.issued | 2016-11-07 | |
dc.description.resumo | In this work, the synthesis of zeolites using 1-butyl-3-methylimidazolium chloride [C4MI]Cl as a structure-directing agent was investigated. The organic cation shows effectiveness and selectivity for the syntheses of TON zeolites under different reaction conditions compared to the traditional structuredirecting agent, 1,8-diaminooctane. The 1-butyl-3-methylimidazolium cation lead to highly crystalline materials and its role as OSDA in our synthesis conditions has been confirmed by characterization techniques. ICP-OES confirms the presence of Al in the samples and 27Al MAS NMR analysis indicated that aluminum atoms were incorporated in tetrahedral coordination. Scanning electron microscopy indicated that changing the crystallization condition (static or stirring), zeolites with different crystal size were obtained, which consequently affects the textural properties of the zeolites. Moreover, varying some synthesis parameters MFI zeolite can also be obtained | pt_BR |
dc.identifier.citation | LOPES, Christian Wittee; VILLARROEL-ROCHA, Jhonny; SILVA, Bernardo Araldi da; MIGNONI, Marcelo Luis; PERGHER, Sibele Berenice Castellã. Synthesis and Characterization of Al-TON Zeolite Using a Dialkylimizadolium as Structure-Directing Agent. Materials Research, [s.l.], v. 19, n. 6, p. 1461-1468, 7 nov. 2016. ISSN 1980-5373 versão online. Disponível em: https://www.scielo.br/scielo.php?script=sci_arttext&pid=S1516-14392016000601461&lng=en&tlng=en. Acesso em: 06 jul. 2020. http://dx.doi.org/10.1590/1980-5373-mr-2016-0041. | pt_BR |
dc.identifier.doi | 10.1590/1980-5373-mr-2016-0041 | |
dc.identifier.issn | 1516-1439 | |
dc.identifier.uri | https://repositorio.ufrn.br/jspui/handle/123456789/29464 | |
dc.language | en | pt_BR |
dc.publisher | Scielo | pt_BR |
dc.rights | Attribution 3.0 Brazil | * |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/br/ | * |
dc.subject | 1-butyl-3-methylimidazolium | pt_BR |
dc.subject | Zeolite synthesis | pt_BR |
dc.subject | TON zeolite | pt_BR |
dc.title | Synthesis and Characterization of Al-TON Zeolite Using a Dialkylimizadolium as StructureDirecting Agent | pt_BR |
dc.type | article | pt_BR |
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