Navegando por Autor "Maurera, M. A. M. A. de"

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Thermal study of CoxZn7-xSb2O12 spinel obtained by pechini method using different alcohols
(Springer, 2004-02) Gouveia, Deiby Santos; Rosenhaim, R.; Maurera, M. A. M. A. de; Lima, Severino Jackson Guedes; Paskocimas, Carlos Alberto; Silva, Elson Longo da; Souza, Antônio Gouveia de; Santos, Ieda Maria Garcia dos
With the aim of obtaining materials with applications in pigments, CoxZn7–xSb2O12 spinels were synthesized using the Pechini method. This method consists in the formation of a polymeric net, where the metallic cations are homogeneously distributed. In this work, two types of alcohol (ethyl glycol and ethylene glycol) were used for the synthesis of a zinc antimoniate spinel, CoxZn7–xSb2O12 (x=0–7). The materials were characterized by termogravimetry (TG) and differential thermal analysis (DTA). TG results indicated a decrease in total mass loss when cobalt was added to the solution substituting zinc, for samples prepared using the two different alcohols. Decomposition temperatures, obtained by TG and DTA, presented a decreasing behavior as cobalt was added to the material. In relation to the alcohols, all results indicated a better polymerization of the resin when ethylene glycol was used, being the most indicated one for cation immobilization. X-ray diffraction did not show differences between the two alcohols – both presented the spinel phase (Co, Zn)2.33Sb0.67O4. Samples with higher quantity of cobalt also presented ilmenite phase (Co, Zn)Sb2O6

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